Packing polymorphism of dicarbonyl-[2-(phenylamino)pent-3-en-4-onato]rhodium(I)
نویسندگان
چکیده
منابع مشابه
4-(3-Nitrophenyl)-3-(phenylsulfonyl)but-3-en-2-one
The C=C double bond in the title mol-ecule, C(16)H(13)NO(5)S, has an E configuration. The crystal structure is stabilized by C-H⋯O hydrogen bonds. There is also a weak C-H⋯π-ring inter-action in the structure.
متن کامل(E)-4-(4-Methoxyphenyl)but-3-en-2-one
In the title compound, C(11)H(12)O(2), the dihedral angle between the benzene ring and the but-3-en-2-one group is 4.04 (5)°. The crystal packing features chains, parallel to [-101], composed of dimers connected by weak C-H⋯O inter-actions..
متن کامل4-(2,6-Dibromo-4-fluoroanilino)pent-3-en-2-one
The title enamino-ketone, C(11)H(10)Br(2)FNO, has a roughly planar pentenone chain; the maximum displacement of an atom from the pentenone plane is 0.071 (4) Å. The dihedral angle between the benzene ring and the pentenone unit is 77.2 (1)°. Inter-molecular C-H⋯Br and C-H⋯O inter-actions, as well as an intra-molecular N-H⋯O inter-action, are observed. In both methyl groups, each H atom is disor...
متن کامل4-[(4-Methylphenyl)amino]pent-3-en-2-one
The title enamino-ketone, C(12)H(15)NO, is a derivative of 4-(phenyl-amino)-pent-3-en-2-one with an approximately planar pentenone backbone, the greatest displacement from the plane being 0.042 (1) Å; the asymmetry in C-C distances in the group suggests the presence of unsaturated bonds. The dihedral angle between the benzene ring and the pentenone plane is 29.90 (4)°. In the crystal, an intra-...
متن کاملButylbis[μ-4-(2,4,6-trimethylphenylamino)pent-3-en-2-onato][4-(2,4,6-trimethylphenylamino)pent-3-en-2-onato]dimagnesium
The structure of the title compound, [Mg(2)(C(4)H(9))(C(14)H(18)NO)(3)], contains two Mg atoms bridged by two μ(2)-O atoms from two of the three ketiminate ligands, while the third ketiminate is strictly chelating to one of the Mg atoms, which is thereby five-coordinate. In place of a chelating ligand, the second Mg atom is ligated by a single terminal n-butyl group and thus is four-coordinate....
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ژورنال
عنوان ژورنال: Journal of Organometallic Chemistry
سال: 2017
ISSN: 0022-328X
DOI: 10.1016/j.jorganchem.2017.09.039